P, Murugan and Soundaran Jeevarathinam, Ananthakrishnan and Narayanasastri, Somanathan and Debasis, Samanta and Asit Baran, Mandal
(2015)
Nanoscale Functionalization of Surfaces by Graft-Through
Sonogashira Polymerization.
RSC Advances , 5.
pp. 4121-4125.
Abstract
Graft through Sonogashira polymerization was used to functionalize various surfaces with conjugate polymers in a
dimension of less than 100 nm. Atomic force microscopy measurement revealed a dense surface coverage with several closely
packed islands. UV-vis spectroscopy and cyclic voltametry measurements suggested a moderate band gap, which is
important for various applications in material science. A device was fabricated using polymer functionalized ITO and
deposited aluminium as cathode to determine the current-voltage (I-V) characteristics and charge carrier mobility. Space
charge limited current method indicated moderate charge carrier mobility while I-V characteristic data indicated its
behaviour as semiconducting material.
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